Product ID:BITUMASTIC 50, 52101001
MSDS Date:02/01/1990
FSC:8030
NIIN:00-265-8121
MSDS Number: BRGHZ

KOP-COAT INC

436 7TH AVENUE
PITTSBURGH, PA 15219
US

Emergency Phone: 800-548-0489/800-424-9300 CHEMTREC

Info Phone: 800-932-2239

Preparer: C A HOPE

Cage: 00297

KOP-COAT INC

PITTSBURGH, PA 15219-1818 US

Telephone: 800-553-5631, CHEMTREC 800-424-9300

Cage: 00297

COAL TAR PITCH

CAS: 65996-93-2

RTECS: GF8655000

Fraction By Weight: <20%(WT)

OSHA PEL .2 MG/M3

ACGIH TLV: 0.2 MG/M3

CREOSOTE (SARA III)

CAS: 8001-58-9

RTECS: GF8615000

Fraction By Weight: <25%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

*

CAS: 65996-79-4

RTECS: GF8635000

* NAPHTHALENE (SARA III)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: <2%

OSHA PEL 10 PPM/STEL 15 PPM

ACGIH TLV: 10 PPM, 52 MG/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

* INDENE

CAS: 95-13-6

RTECS: NK8225000

Fraction By Weight: <15%

OSHA PEL 10 PPM, 45 MG/M3

ACGIH TLV: 10 PPM, 48 MG/M3

* BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <0.5%

OSHA PEL 10 PPM/CEIL 25 PPM

ACGIH TLV: 10 PPM, 32 MG/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

* XYLENE (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <2%

OSHA PEL 100 PPM/STEL 150 PPM

ACGIH TLV: 100 PPM/STEL 150 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TALC

CAS: 14807-96-6

RTECS: WW2710000

Fraction By Weight: <25%

OSHA PEL 2 MG/M3 RESPRBL DUST

ACGIH TLV: 2 MG/M3 RESPRBL DUST

354 GRAMS/LITER

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE; EYE: IRRIT, CORNEAL CHANGES.
SKIN: IRRIT, ACCENTUATED BY SUNLIGHT. ABSORBED THRU SKIN (INTERNAL
ORGAN DAMAGE, DEATH). CONTACT W/HEATED MATERIAL CAN CAUSE THERMAL
BURNS. INHAL: RESP TRACT IRRIT. INGESTION: GI DISTURBANCES,
IRRITATION, NAUSEA, VOMITING, ABDOMINAL PAIN, CARDIOVASCULAR
INVOLVEMENT.
Explanation of Carcinogenicity:IARC:SUFFICIENT EVIDENCE IN HUMANS FOR
CREOSOTE, COAL TAR PITCH, BENZENE. NTP:CREOSOTE CARCINOGEN IN
ANIMALS, BENZENE.
Effects of Overexposure:CHRONIC;SKIN:REPEATD/PROLONGD CONTACT MAY CAUSE
MORE SERIOUS SKIN DISORDERS (CANCER). INHALATION:
REPEATED/PROLONGED CONTACT TO HIGH CONCENTRATIONS OF VAPOR MAY
RESULT IN RESPIRATORY DIFFICULTIES, CEN TRAL NERVOUS SYSTEM EFFECTS
(DIZZINESS,UNCONSCIOUSNESS, COLLAPSE, DEATH). CHRONIC OVEREXPOSURE
MAY LEAD TO LUKEMIA.
Medical Cond Aggravated by Exposure:HISTORY OF LIVER, KIDNEY, SKIN,
EYE, CNS, RESP SYSTEM, BLOOD FORMING ORGANS OR W/BLEEDING
ABNORMALITIES, OR EXPOSURE TO HARMFUL MAT'LS TO THOSE SYSTEMS ARE
AT GREATER THAN NORMAL RISK WHEN EXPOSED.

First Aid:EYE:IMMED FLUSH W/WATER 15 MIN.GET MED AID.SKIN:WASH W/SOAP &
WATER/WATERLESS HAND CLEANR.CONTACT W/MOLTEN PRODUCT,DONT REMOVE
CONTAM CLOTH.FLUSH SKIN IMMED W/COLD WATER.IMMERSE IN COLD
WATER.PACK W/I CE.GET MED AID.INHAL:REMOVE FROM EXPOSURE.IF
BREATHING STOPPED/DIFFICULT, GIVE ARTIF RESP/OXYGEN AS NEEDED.GET
MED AID.INGEST:DONT INDUCE VOMIT.GIVE 1-2 GLASSES MILK.GET MED
AID.NOTHING TO UNCONSCIOUS

Flash Point Method:PMCC
Flash Point:100F,38C
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, FOAM, OR WATER
SPRAY. WATER OR FOAM MAY CAUSE FROTHING, IF MOLTEN.
Fire Fighting Procedures:WEAR FIRE SERVICE PROTECT EQUIP INCLUDING
FULL-FACE MSHA/NIOSH SCBA. USE WATER TO COOL FIRE-EXPOSED
CONTNR/STRUCTR/PROTECT PERSONNEL. FIRE MAY EMIT TOXIC VAPORS
Unusual Fire/Explosion Hazard:VAPOR/DECOMPOSITION PRODUCTS MAY BE
RELEASED FORMING FLAMMABLE/EXPLOSIVE MIX IN AIR. CLOSED CONTAINER
MAY EXPLODE W/HEAT. VAPOR HEAVIER THAN AIR, MAY FLASHBACK.

Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED. STAY UPWIND.
SMALL SPILLS: TAKE UP WITH SAND OR OTHER NONCOMBUSTIBLE ABSORBENT
MATERIAL. FLUSH AREA WITH WATER. DIKE LARGE SPILLS FOR LATER
DISPOSAL. CONTAIN RUNOFF FROM FIRE CONTROL AND DILUTION WATER.

Handling and Storage Precautions:AVOID PROLONGD/REPEATD VAPOR
BREATHING.AVOID PROLONGD/REPEATD SKIN/EYE CONTACT.DONT USE AROUND
HOUSE.DONT EAT.DONT USE TILL CAUTIONS UNDERSTOOD.
Other Precautions:APPLIC OF CERTAIN PROTECTIVE CREAMS (SUN SCREENS)
BEFORE WORKING/SEVERAL TIMES DURING WORK MAY BE BENEFICIAL.STORE IN
AREAS/BLDGS IN COMPLY W/OSHA 1910.106.KEEP IN CLOSED, LABELED CNTNR
IN COOL, DRY V ENTED AREA.PROTECT FROM PHYSICAL DAMAGE.

Respiratory Protection:IF ABOVE TLV/PEL, USE NIOSH/MSHA UNITS PER 29
CFR 1910.134 & MFR'S "INSTRUCTIONS" & "WARNINGS". COMBINATION
FILTER/ORGANIC VAPOR CARTRIDGES/CANISTER MAY BE USED. FULL FACE
PIECE RESPIRATORY PROTECTIVE UNITS REQUIRED.
Ventilation:GENRL/LOCAL EXHAUST TO KEEP BELOW TLV/PEL & LFL.LOCAL
EXHAUST NEEDED FOR ENCLOSD/CONFIND SPACE.OSHA REQ/NIOSH PUB 80-106
Protective Gloves:INDUSTRIAL RESISTNT FLEXIBLE TYPE GLOVES
Eye Protection:SAFETY GLASSES, GOGGLES, SIDE/FACE SHLDS
Other Protective Equipment:INDUST WK CLOTHES & SAFETY
FOOTWEAR.IMPERVIOUS PROTECTIVE GARMENTS (HEAD/NECK
COVER,APRON,JACKET,PANTS,COVERALLS,BOOTS).
Work Hygienic Practices:OBSERVE INDUST HYGIENE PRACTICES & RECOMMNDD
PROCEDURES.WASH PROMPTLY AFTER CONTACT BEFORE EAT,DRINK,USE
TOBACCO,RESTRM.
Supplemental Safety and Health

HCC:F4
Evaporation Rate & Reference:VERY SLOW (BU AC=1)
Solubility in Water:NIL
Appearance and Odor:BLACK LIQUID WITH COAL TAR ODOR
Percent Volatiles by Volume:32

Stability Indicator/Materials to Avoid:YES
AVOID OXIDIZING MATERIALS. AVOID CONTACT WITH PVC PIPE.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:TOXIC FUMES

Waste Disposal Methods:IGNITABLE HAZARDOUS WASTE. DISPOSE IN ACCORDANCE
W/LOCAL, STATE & FED REGS. PLACE IN LABELED, SEALED CONTAINER.
RESPORT RELEASED PRODUCT TO NAT'L RESPONSE CENTER (800-424-8802).
RQ 100 LBS. IN CALIF D ISPOSE AS HZD WASTE, ELSEWHERE, INDUSTRIAL
WASTE.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.